![]() ![]() Since its initial release in 2020, it has amassed a devoted following of readers from around the world. However, as an illustration, consider, a website that allows users to download YouTube films they’ve submitted themselves. There are a lot of YouTube downloading tools available on the internet. ![]() How can you find our Youtube Downloader tool?
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![]() ![]() Redcat SixtyFour - Radio Firmware Update InstructionsĬheck out the Redcat SixtyFour Quick Start Video Guide: Visit YouTube - Redcat SixtyFour Quick Start Guide.Momentary buttons for lowering either the front or rear to minimum ride height.Momentary switches for raising either the front or rear to max ride height / hopping.Individual switches for each of the 3 height adjustment servos.6-Channel LR6X Radio control with lowrider style switches.Two 25KG rear axle height adjustment servos.Ultra fast custom made REEFS RC Hopping Servo.Patented vehicle hopping system - U.S.Officially licensed and highly detailed 1964 Chevrolet Impala SS body.Using specialty servos and precision weight bias, it replicates the driving style and overall look of a full sized lowrider / hopper. The SixtyFour is designed for slow cruising and performing tricks that you can only do with special hydraulically actuated suspensions. The attention to detail continues below the body, with the chassis frame, faux transmission and functional solid rear axle with removable differential cover. Clear windows feature high quality chrome foil trim to complete the ultra-realistic appearance. Optional LED lights are available for night time cruising. 23 individual chrome plated molded parts are used to create the body’s accessories. The Impala SS interior and exterior badging adorn the 1964 Impala SS body and interior. The SixtyFour was designed from the ground up with the lowrider, auto enthusiast and R/C scaler communities in mind.Įvery detail of the SixtyFour was painstakingly and passionately created with scale accuracy and detail. All Gears: Differential, Idler, Pinion, & Spurġ964 Chevrolet Impala SS - Fully Functional Hopping LowriderĮxpertly designed and engineered, the Redcat SixtyFour hopping lowrider captures the 1964 Chevrolet Impala SS in a classic highly-detailed, fully-functioning 1:10 scale Remote Control Car.Gears: Differential, Idler, Pinion, & Spur.All Cars, Crawlers, Trucks, Buggies & Truggies.Cars, Crawlers, Trucks, Buggies & Truggies. ![]() ![]() ![]() Cats who have grown accustomed to a certain litter might decide that they dislike the smell or feel of a different litter. These sensitivities can also influence a cat’s reaction to her litter. Some cats develop preferences for eliminating on certain surfaces or textures like carpet, potting soil or bedding.Īs predators who hunt at night, cats have sensitive senses of smell and touch to help them navigate through their environment. Cats usually prefer one to two inches of litter. The litter in your cat’s box is too deep.Your cat’s litter box has a hood or liner that makes her uncomfortable.Your cat can’t easily get to her litter box at all times.Your cat’s litter box is too small for her.Be sure to have a litter box for each of your cats, as well as one extra. You haven’t provided enough litter boxes for your household.You haven’t cleaned your cat’s litter box often or thoroughly enough.The following common litter-box problems might cause her to eliminate outside of her box: If your cat isn’t comfortable with her litter box or can’t easily access it, she probably won’t use it. Why Do Some Cats Eliminate Outside the Litter Box? ![]() Be certain to read the entire article to help you identify your particular cat’s problem and to familiarize yourself with the different resolution approaches to ensure success with your cat. Behavioral treatments are often effective, but the treatments must be tailored to the cat’s specific problem. Litter box use problems in cats can be diverse and complex. If your cat does eliminate outside her box, you must act quickly to resolve the problem before she develops a strong preference for eliminating on an unacceptable surface or in an unacceptable area. It is also important that you pay close attention to your cat’s elimination habits so that you can identify problems in the making. See our common litter-box management issues below, and our ways to make litter boxes cat-friendly. The best approach to dealing with these problems is to prevent them before they happen by making your cat’s litter boxes as cat-friendly as possible. Once a cat avoids her litter box for whatever reason, her avoidance can become a chronic problem because the cat can develop a surface or location preference for elimination-and this preference might be to your living room rug or your favorite easy chair. Elimination problems can develop as a result of conflict between multiple cats in a home, as a result of a dislike for the litter-box type or the litter itself, as a result of a past medical condition, or as a result of the cat deciding she doesn’t like the location or placement of the litter box. Still others eliminate both in and out of their boxes. Some only use their boxes for urination or defecation but not for both. At least 10% of all cats develop elimination problems. ![]() ![]() ![]() ![]() ![]() Opens a text input where you can type an item name to search for. Right-click the script icon in your system tray and select PoE Item Info Settings to open the settings window and to edit both PoE-ItemInfos and PoE-TradeMacros settings. Make sure to play Path of Exile in english, if you're using a different language it probably won't work.A lot of options, including the league can be changed by opening the settings window or editing config_trade.ini.Default league is set to tmpstandard (Softcore Temp-League).Make sure to run PoE in (borderless) windowed mode.Download the latest release and extract the zip-file.PSA: If AHK crashes when starting TradeMacro try and use a different version, AutoHotkey_1.1.26.01 should always work. When in doubt ask other people or do some manual checks. Use the tools average and median prices to quickly judge if the first results could be accurate or totally wrong. Inform yourself about what this tool can do and what not (FAQ for example). Never completely trust any price checking tool. TradeMacro will be updated to always have the latest PoE-ItemInfo code, you don't have to run their script since it's included here. (Before TradeMacro version 2.15.3 ctrl was used instead of alt as defaults). You can also open the items wiki page via alt+w or open the item search on poe.trade instead via alt+q. With TradeMacro, price checking is added via alt+d, alt+shift+d or alt+i. This builds on top of PoE-ItemInfo which provides very useful item information on ctrl+c. PoE TradeMacro is an Autohotkey (AHK) script that provides several convenient QoL features for Path of Exile Trading. ![]() ![]() Iconizer - Create Xcode image catalogs (xcassets) on the fly.IconGenerator - A macOS app to generate app icons. ![]() car files and browse/extract their images. Asset Catalog Tinkerer - An app that lets you open.Attabench - Attabench is a microbenchmarking app for macOS, designed to measure and visualize the performance of Swift code.AppleEvents - The unofficial Apple Events app for macOS.Cleaner for Xcode - Cleaner for Xcode.app built with react-native-macos.SmartPush - iOS Push Notification Debug App.iOS Images Extractor - iOS Images Extractor is a Mac app to normalize, decode and extract images from iOS apps.WWDC - The unofficial WWDC app for macOS.Touch Bar Simulator - Use the Touch Bar on any Mac.Knuff - The debug application for Apple Push Notification Service (APNs).CocoaRestClient - A free, native Apple macOS app for testing HTTP/REST endpoints.gitbar - Open source github contribution stats on your Mac OS X Menu Bar.GitUp - The Git interface you've been missing all your life has finally arrived.GitHub Desktop - Simple collaboration from your desktop.Galeri - A perpetual artwork streaming app.Google Allo for Desktop - A native OS X & Windows desktop app for Google Allo.Rambox - Free, Open Source and Cross Platform messaging and emailing app that combines common web applications into one.Telegram - Source code of Telegram for macos on Swift 4.0.Telegram - Source code of deprecated Telegram for macos version.Caprine - Elegant Facebook Messenger desktop app.Electronic WeChat - A better WeChat on macOS and Linux.Textual - Textual is an IRC client for OS X.Telegram Desktop - Telegram Desktop messaging app.ChitChat - A native Mac app wrapper for WhatsApp Web.Simpo - A macOS menubar app to post status quickly.Ramme - Unofficial Instagram Desktop App.Caprine - An elegant Facebook Messenger desktop app.Goofy - Unofficial Facebook Messenger client.Screenbar - A MacOS menubar app for automating screenshots.Freehand - A MacOS Status Bar App for quick sketch.WebPonize - WebPonize is a Mac OS App for converting PNG, JPEG, animated (or not) GIF images into WebP.ImageAlpha - Mac GUI for pngquant, pngnq and posterizer.Imagine - Imagine is a desktop app for compression of PNG and JPEG, with a modern and friendly UI.DeezPlayer - Deezer Desktop app for Windows, Linux and macOS.lyricsify - A simple Spotify lyrics viewer menu bar app for macOS in Swift.Caption - Caption takes the effort out of finding and setting up the right subtitles.WebTorrent Desktop - The streaming torrent app. ![]()
![]() ![]() The pI of amino acids with acidic side chains More complex amino acids have more than two pK a values due to the presence of additional pK a values for their side chains. The isoelectric point can, therefore, be approximated by averaging the two pK a values. If the pH s increased to that of the pK a of the amino group (9.60), another buffer is produced where there is an equilibration between the protonated neutral zwitterion and the deprotonated negative amino acid. This pH produces the carboxyl buffer zone. For example, when the pH = 2.34 (pK a of glycine), the solution comprises of 50% neutral molecules in which the carboxyl is deprotonated, and 50% positive molecules where the carboxyl is protonated. When the pH is exactly at the pK a value, a buffer arises in which the deprotonated and protonated amino acids exist in equilibrium. How does the zwitterionic form of an amino acid relate to the pI? The zwitterionic form of the amino acid can exist at any pH value between pK a1 and pK a2. The amino acid now carries a net negative charge of -1. When the pH> pK a2, the amino group is deprotonated and loses its charge. This represents the zwitterionic form of the amino acid as it simultaneously possesses a positive and negative charge. When the pHpH> pK a1), the carboxyl group is deprotonated while the amino group remains protonated. Bariatric surgery associated with long-term improvements in pain, physical function, work productivity.Air pollution may trigger arrhythmias in healthy adolescents.Disruption of actin cytoskeleton is key to triggering human immune response, research finds.This is illustrated below using glycine, which has two pK a values – pK a 1 represents the (de)protonation of the carboxyl group and pK a2 represents the (de)protonation of the amine group: For example, if there were two pK a values, three structures can be discerned. There is always one more structure than the number of pK a values for amino acids. ![]() Amino acids possess distinct pK as for the carbonyl group, amino group, and any functional groups on the side chain that may be protonated or deprotonated. PK a relates to the equilibrium constant and defines the transition between two structural forms of an amino acid–protonated and deprotonated. The net charge of the protein is determined by summing the charge of individual amino acids across the protein. The pK a for an amino acid is an acid dissociation constant that refers to the equilibrium between the protonated and deprotonated forms of the backbone amino group, backbone carboxyl group, and any potential acid/base component of the variable group. What is the relationship between the pH and pK a of an amino acid? A zwitterionic amino acid consists of a negative carboxylate ion and a positive ammonium ion alongside a charge on their side chain, which varies between amino acids. ![]() Zwitterion possesses discrete functional groups, each of which carry a positive or negative charge. The isoelectric point corresponds to what is known as the zwitterionic form of a protein. This charge is also dependent on the pH of the surrounding solution. Each of the amino acids in a protein carries a distinct charge, and the overall charge of a protein is the summation of the individual charges on each amino acid. pI is most commonly examined for proteins. The isoelectric point (pI) is the point at which the net charge on a molecule is zero. By lysine the side chain $-(CH_2)_4\mboxOH$ is an even weaker acid $$ so the IEP is 5.66Īnd every amino acid has more or less contribution to the IEP of a protein.By Hidaya Aliouche, B.Sc.By glycine the side chain $-H$ is neutral (while the amino and carbonic acid groups are not) so the IEP is 5.97.This isoelectric point depends on the side chains: Every amino acid has a different isoelectric point: a pH where they do not carry electric charge. ![]() ![]() ![]() This waterfall involved a lot of bushwacking to get to, but was worth it. The salamanders usually move too quickly to get a photo, I think the cold water might have slowed him down a bit. I wasn't very close to him, this is zoomed in and then heavily cropped. The friend disappeared immediately, but this guy stuck around for a bit. This one (and a friend) were in the Red River. I caught a glimpse of an otter in a tributary of the Red River a couple years ago, but it disappeared very quickly. and if it has been raining, you sometimes get a double waterfall. This one is right off an official trail (i.e. We haven't seen an arch until now, but the gorge is packed with them. There will be less commentary and fewer photos from now on. and that is just a couple different day hikes in September. and if you know where to look, there is often a waterfall just around the corner. more animal life (only seen one of these before). and there are always creeks somewhere nearby. The gorge has lots of flowers for most of the year. Note: the vast majority of these photos were taken from non-official or non-existent trails.Ī Year (plus a little bit more) in the Red River Gorge ![]() But still an amazing place with lots to be grateful for, "the gorge" is a special place. I read this post a couple years ago and immediately thought of the RRG, very popular, very crowded, full of tourists. It is a very popular place full of tourists. I've have never seen Delicate Arch in person (it's in Utah), but I've seen lots of photos. I managed to stay on top of backpacking trip reports but always had this huge backlog of day hiking photos to deal with.įor the last couple of months I have had this post ( Ode to Delicate Arch) from as blogging inspiration. The video showcased new content for players to try out. It became harder to process photos and then post them as the number of photos started to increase, in other words, I started to procrastinate. Game developer Klei Entertainment recently released a new trailer for Don’t Starve Together: The Gorge Event. I started out posting individual trip reports for each day and then quickly fell behind. It encouraged me to get way off the trail to see what I could find. I owe a lot of inspiration for the following photos and the day hiking to this post about waterfalls in the Red River Gorge on. I have done a lot of day hiking in the Red River Gorge in the last couple of years (about 35 days in the last 15ish months). I did not know where to post this, since it is not really backpacking (only one night), but a lot of day hikes. ![]() ![]() ![]() You no longer have to fantasize about being a goat, your dreams have finally come true Gameplay-wise, Goat Simulator is all about causing as much destruction as you possibly can as a goat. Goat Simulator Free In-App Purchases all unlocked. Goat Simulator is the latest in goat simulation technology, bringing next-gen goat simulation to YOU. In-game physics that bug out all the timeĪndroid TV users: a compatible gamepad is required to play.MILLIONS OF BUGS! We're only eliminating the crash-bugs, everything else is hilarious and we're keeping it.Get points for wrecking stuff - brag to your friends that you're the alpha goat. ![]() Goat Simulator is a completely stupid game and, to be honest, you should probably spend your money on something else, such as a hula hoop, a pile of bricks, or maybe pool your money together with your friends and buy a real goat. You can play both Xbox 360 titles on your Xbox One with Backward. When it comes to goats, not even the sky is the limit, as you can probably just bug through it and crash the game. Games with Gold: Goat Simulator and Super Meat Boy now available as free downloads. It has been compared to an old-school skating game, except instead of being a skater, you're a goat, and instead of doing tricks, you wreck stuff. Gameplay-wise, Goat Simulator is all about causing as much destruction as you possibly can as a goat. You no longer have to fantasize about being a goat, your dreams have finally come true! ![]() Goat Simulator is the latest in goat simulation technology, bringing next-gen goat simulation to YOU. Goat Simulator is a completely stupid game and, to be honest, you should probably spend your money on something else, such as a hula hoop, a pile of bricks, or maybe pool your money together with your friends and buy a real goat. ![]() ![]() ![]() Relay_Log_File: cluster1-pxc-0-relay-bin-ps_to_pxc1. Slave_IO_State: Waiting for master to send event ![]() Kubectl exec -it cluster1-pxc-0 -c pxc - mysql -uroot -proot_password -e "show replica status \G" Deploy Percona Distribution for MySQL Operator on Kubernetes (I have used GKE 1.20). Migration Configure the target PXC cluster managed by k8s operator:ġ. Configure asynchronous replication between MySQL server and PXC cluster managed by k8s operator.Īs a result, we have asynchronous replication between MySQL server and PXC cluster in k8s which is in read-only mode. Perform the restore of the MySQL database from the S3 bucket into the PXC cluster which is deployed in k8s.ģ. Make the MySQL database backup using Percona XtraBackup and upload it to the S3 bucket using xbcloud.Ģ. The following steps should be done to perform the migration procedure:ġ. AWS S3 bucket is used to save the backup from MySQL DB and then to restore the PXC cluster in k8s. Google Kubernetes Engine (GKE) cluster where Percona Distribution for MySQL Operator is deployed with PXC cluster (as a target).ģ. Depending on your topology of DB deployment, you can use several servers to use synchronous connection failover mechanism on the operator’s end.Ģ. In my test deployment, I use only one server as a Source to simplify the deployment. Millions of queries per second Hundreds of. MySQL 8.0.23 database (in my case it is Percona Server for MySQL ) which is deployed in DO (as a Source) and Percona XtraBackup for the backup. Built at Google to scale, Vitess is proven as the most scalable open source database out there. ![]() This approach helps you reduce downtime and data loss for your application.ġ. Connect Datadog ![]() Refocusing on mobile apps brought me closer to the goal. I did not include such travel blogs in my comparison below. Until they have a companion mobile app like WordPress has one, writing on the go will be awkward. ![]() Alas, as much as I got hyped reading its features, one point immediately cooled me off―although it’s mobile-friendly, it is web-based and requires internet to function, an obstacle in a wild remote location. I first thought of a cool-looking personal online travel blog and Exposure kept coming up and recommended as a solid and handy solution. Photos themselves tell stories but how about non-visual stories and observations? What goes past Instagram? You can write a post about your thoughts but how do you later piece it all together? Have you tried looking up your Facebook non-photo posts from 3 years ago? How can you tell a complete story to your child when she grows up? A dedicated electronic travel journal―as a unified medium that collects your notes, thoughts, details, photos, videos, etc.―still seems to be the best approach so this is the one I decided to take for my next trip. Of course, with the proliferation of technology, trips like that in 2014 get a fair chance of being recorded through mobile photography and a favorite social network. My attempt to bring an elaborate pocket diary to my 3rd trip to India in 2014 failed―I only wrote one record. I had lots of spare time but not as much later. I love writing and expressing myself epistolary so the former was a joy for me in my youth, such as this diary from 1996 when I was traveling between Moldova, Romania, Russia, and the US. There are two main approaches to travel journal writing: traditional pen-and-paper and electronic (social media posts, dedicated diary apps, Evernote, etc.). None of the mentioned app developers were advised of this research. I then realized that the massive data I put together would be a shame to bury and it may help someone else―I wish I found an overview like this a few weeks ago! What follows is my unbiased personal take on the travel journal apps which I formed for myself and then polished for my friends. ![]() I’m a type of researcher who digs deep and throws everything in the comparison tables to crunch and rate the findings. What will be left of it in 20 years? In my preparations for India trip in a few weeks I decided to try changing it and find a versatile and engaging tool. TripIt, through which I’ve been logging almost all my itineraries since that year, tallies my journeys to about 207,000 miles in 22 countries, a little short of reaching the moon! Do I remember much of it? Perhaps on the surface, with spotty bursts of memories. Year 2008 was a milestone for me when I made my first business trip to Alaska. How do you keep your loved ones and friends abreast of your travels? Can you recollect all details of your 5-year-old trip to an exotic land? Is going back to Instagram or Facebook the best you can do? Here’s a traveling photographer’s comprehensive research and thorough unbiased review of 5 best travel journal apps.Ģ07,000 milesīeing a professional photographer opens many doors, including those far and away. ![]() |
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